• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Methods of assembling dissimilar high temperature alloys are provided along with articles (100), such as aerodynamic turbine profiles, made by the process. The method includes inserting a barrier material between a first segment (110) and a second segment (120) to form a segment assembly. The first segment comprises a titanium aluminide material and the second segment comprises a nickel alloy. The barrier material comprises a primary constitutive element present in the barrier material in a concentration of at least about 30% by weight of the barrier material, and the primary constitutive element is a group 1B, group 4B (titanium and zirconium only) group 5B, group 6B transition metal element. Group 7B or Group 8B (nickel only). The segment assembly is bonded in the solid state at a combination of temperature, pressure and time effective to establish a metallurgical joint between the first and second segments, thereby forming an intermediate article; and the intermediate article is heat treated to form a bonded article (100).
    公开号:CH709882B1
    申请号:CH01068/15
    申请日:2015-07-21
    公开日:2016-09-15
    发明作者:Zhao Qi；John Buresh Steve；Supatarawanich Dheeradhada Voramon；Sloan Marte Judson；Zhang Wanming
    申请人:Gen Electric；
    IPC主号:
    专利说明:

    State of the art
    This disclosure generally relates to solid state metallurgical bonding processes of various high temperature materials, in particular to methods of joining titanium containing alloys to nickel based materials. More particularly, this disclosure relates to the solid state bonding of titanium aluminide alloys to nickel base superalloys and articles made using such processes.
    The choice of a specific alloy for use in a given engine component design, such as a gas turbine engine component, is made based on the critical design requirements for a number of material properties, including strength, toughness, environmental resistance, weight, cost, and others. When an alloy is used to construct the entire component, compromises must be made in terms of component performance because no single alloy has ideal values for the long list of properties required for the application, and because conditions of temperature, stress, Impact of foreign substance and other factors are not uniform over the entire component surface.
    It would be advantageous if the performance of machine components could be improved to better withstand aggressive conditions present in localized areas. However, it would not be desirable if improvements of a property were made at the expense of other critical design requirements of the component. Therefore, it would be beneficial if turbine components and other components of high temperature engines could be improved in a manner that would allow, for example, improved performance in regions subject to harsh stress and temperature conditions without significantly affecting the overall performance of the component.
    One way to achieve the result described above is to attach segments at certain points of the component, where the segments are made of materials having properties optimized for conditions specific to their respective positions, and Assemble segments to form an overall component that has strategically distributed location-specific properties. However, this strategy assumes the presence of joining methods that are suitable for joining the segments. While conventional methods, such as welding and brazing, are sufficient for certain combinations of materials under certain circumstances, there remain substantial limitations on the type of materials that can be joined and the conditions under which the joint would provide suitable properties.
    Therefore, there remains a need for joining methods that are suitable for joining advanced high temperature materials to form composite structures that have sufficient properties for use in demanding applications, such as gas turbine engine plants. A need continues to exist for strategically designed components where a required distribution of properties can be achieved by using locally optimized material compositions and structures.
    Short description
    The present invention provides a solution to meet these and other needs. The invention relates to a method for metallurgical solid state bonding of various high temperature materials. The method includes inserting a barrier material between a first segment and a second segment to form a segment assembly. The first segment comprises a titanium aluminide material and the second comprises a nickel alloy. The barrier material comprises a primary constituent element present in the barrier material in a concentration of at least 30% by weight of the barrier material, and the primary constituent element is a Group 1B, Group 4B (exclusively titanium and zirconium) transition metal, Group 5B, Group 6B, Group 7B or Group 8B (nickel only). The segment assembly is bonded in the solid state at a combination of temperature, pressure and time to effect a solid state mass transfer by diffusion between the segments and to produce a metallurgical bond between the first and second segments with the barrier material therebetween, thereby producing an intermediate article is formed; and the intermediate article is heat treated to form a bonded article.
    In the above-mentioned method, the primary constitutive element may include niobium or tantalum.
    Additionally or alternatively, the titanium aluminide material may comprise gamma titanium aluminide.
    In the method of any type mentioned above, the inserting may include depositing a layer comprising the barrier material on one or both of the segments.
    In the method of any type mentioned above, the temperature of the bonding step may be in the range of 900 degrees Celsius to 1100 degrees Celsius.
    Additionally or alternatively, the pressure of the bonding step may be in the range of 4 megapascals to 7 megapascals.
    In a further supplement or alternative, the binding step may be carried out in a substantially inert environment.
    In the method of any type mentioned above, the heat treatment of the intermediate article may comprise heating the intermediate article to a temperature in a range of 900 degrees to 1300 degrees.
    Additionally or alternatively, the heat treatment may include a multi-stage heat treatment.
    In the process of any type mentioned above, the nickel alloy may be a nickel base superalloy.
    The joined article may comprise a component for a gas turbine assembly.
    In particular, the component may comprise an aerodynamic profile.
    An embodiment of the method according to the invention comprises inserting a barrier material comprising at least 30 weight percent niobium, tantalum or combinations of one or both thereof between a first segment and a second segment to form a segment assembly. The first segment comprises a gamma titanium aluminide material and the second segment comprises a nickel base superalloy. The method further includes bonding the segment assembly in the solid state at a temperature in the range of 900 degrees Celsius to 1300 degrees Celsius, a pressure in the range of 4 megapascals to 7 megapascals, and in a time necessary to establish a metallurgical joint between the first and second Segments is effective, thereby forming an intermediate article. In addition, the method further comprises heat treating the intermediate article by a multi-stage heat treatment to form a bonded article.
    The invention further relates to a obtained by the inventive method associated article comprising a first part which is connected to a second part by a transition zone. The first part comprises a titanium aluminide material, the second part comprises a nickel alloy. The barrier material comprises a primary constitutive element present in a concentration of at least 30% by weight of the barrier material; the primary constitutive element is a transition metal element of 1B, Group 4B (titanium and zirconium only), Group 5B, Group 6B, Group 7B or Group 8B (all nickel). The transition zone comprises a concentration of primary constitutive element that is higher than a concentration of the constituent element in the first part and in the second part.
    In the above-mentioned article, the primary constitutive element may include niobium, tantalum, or combinations of either or both of these.
    Additionally or alternatively, the transition zone may be substantially free of material having a melting point below 1000 degrees Celsius.
    In the article of any type mentioned above, the nickel alloy may be a nickel base superalloy.
    Additionally or alternatively, the titanium aluminide material may comprise gamma titanium aluminide.
    Any article mentioned above may include an aerodynamic profile component for a gas turbine assembly.
    drawings
    These and other features, aspects and advantages of the present invention will become better understood upon reading the following detailed description with reference to the accompanying drawings, wherein like characters represent like parts, in which: FIG. 1 is a schematic cross-sectional view of an illustrative embodiment of the present invention is.
    Detailed description
    An approximate language as used throughout the specification and claims may be used to modify any quantitative representation that could reasonably vary without altering the basic function to which it pertains , respectively. Accordingly, a value modified by an expression or terms such as "about" and "substantially" is not limited to the exact specified value. In some cases, the approximate language may correspond to the accuracy of an instrument for measuring the value. Here and throughout the specification and claims, range limitations may be combined and / or reversed; Such areas are identified and include all sub-areas contained therein, unless the context or language indicates otherwise.
    In the following description and claims, the singular forms include "a", "an" and "the" plural references, unless the context clearly dictates otherwise. As used herein, the term "or" is not intended to be exclusive and refers to at least one of the present referenced components and includes cases in which a combination of the referenced components , unless the context clearly dictates otherwise.
    As used herein, the terms "may" and "may be" indicate a possibility of occurrence within a set of circumstances, possession of a specific property, characteristic or function, and / or more precisely describe another verb by expressing one or more more of the power, aptitude, or possibility associated with the more precisely determined verb. Accordingly, the use of "may" and "may be" indicates that a modified term is obviously appropriate, capable or suitable for a given ability, function or use, while taking into account that in some circumstances the modified term is sometimes inappropriate , capable or suitable.
    The present invention includes a process for the metallurgical solid state bonding of various high temperature materials. In particular, the method provides solid state diffusion bonding of titanium aluminide materials to nickel base materials, such as superalloys, such bonding enabling the production of components comprising both of these interesting materials. The present invention also includes components made from bonded segments of titanium aluminide and nickel base materials such as nickel base superalloy.
    Diffusion bonding is a joining process in which segments to be joined are contacted at high temperature and pressure levels for a time sufficient to effect a solid state mass transfer by diffusion between segments, thereby providing a metallurgical bond between them the segments is formed. While the process is somewhat expensive compared to welding and brazing, it is often advantageous when such liquid phase assembly techniques are difficult or impossible to successfully apply. In some alloy systems, such as certain nickel-base superalloys and titanium aluminides, welding and brazing are often difficult to successfully employ due to the formation of deleterious phases and / or cracks in the heat-affected zone or due to reaction with filler material. In particular, when attempting to join dissimilar materials, complications may occur where two materials have substantially different responses to filler materials and / or thermal variations during assembly. Diffusion bonding, a solid-state joining process, is therefore an attractive method for assembling dissimilar materials, which presents difficulties in conventional liquid-phase processes.
    According to the present invention, a first segment comprises a titanium aluminide material. A "titanium aluminide material" for purposes of this specification is any class of materials known in the art as titanium aluminide alloys, that is, alloys based on an intermetallic compound, such as titanium and aluminum, such as TiAl or Ti3Al , includes. In contrast, conventional titanium alloys, such as Ti-6% aluminum-4% vanadium (known in the art as "Ti 6-4") are based on various allotropic phases of titanium, such as a hexagonal close-packed alpha phase and body-centered cubic beta phase. Titanium aluminide materials such as those based on gamma titanium aluminide (TiAl) offer an interesting potential alternative to nickel base superalloys in some applications because of their excellent high temperature mechanical and environmental resistance properties in combination with a comparatively low density. In addition to titanium and aluminum, the titanium aluminide material of the first segment may further comprise one or more additional elements commonly used in titanium aluminide based alloys; Examples of such elements include, without limitation, niobium, chromium, tungsten, iron, vanadium, silicon, carbon and boron. Possible phases present in the titanium aluminide material of the first segment include, without limitation, gamma titanium aluminide, borides, carbides, alpha ( hexagonal close packed structure) titanium, beta (body centered cubic) titanium and alpha two (nominal composition Ti3Al) phase.
    A second segment according to the invention comprises a nickel alloy, which means that nickel is present in the highest proportion by weight of all elements present in the alloy. In some embodiments, the alloy belongs to the so-called "superalloy" class. Such alloys generally include various precipitation strengthened nickel alloys in which intermetallic precipitation phases, such as gamma prime (Ni3Al), are dispersed in a face centered cubic ("gamma" or austenite) matrix. Notable but non-limiting examples of such alloys include nickel base superalloys such as GTD-111® (General Electric Co.), GTD-444® (General Electric Co.), IN-738, René <wz> N4 (General Electric Co.). René <wz> N5 (General Electric Co.), René <wz> 108 (General Electric Co.) and René <wz> N500 (General Electric Co.). Nickel base superalloys have been extensively used in high temperature, high stress applications such as turbomachinery components due to their excellent high temperature mechanical properties. In some embodiments, the superalloy of the second segment is in the form of a single crystal, while in other embodiments, the alloy is polycrystalline, such as a directionally solidified material having a plurality of pillar grains having substantially the same orientation. Directionally solidified and single crystalline materials offer improved resistance to creep at elevated temperatures.
    Typically, when a nickel alloy and titanium aluminide article are diffusion bonded using standard practices known in the art, the resulting bond is not acceptable for high temperature applications due to the formation of deleterious phases and structures in the region of the bond. For example, the diffusion of aluminum and titanium from the aluminide into the nickel alloy during heating and bonding to form, during processing, a substantial amount of relatively low melting point material, such as a eutectic phase rich in nickel, titanium and aluminum , to lead. The formation of such a material can lead to undesirable melting during the bonding process. The phases formed in the binding region can also be quite brittle as compared to base metals and when sufficient volume fraction of such a brittle phase is formed, such as when a substantially continuous region of length (or considerable length) of the bond line or when the brittle phase is formed in a network or other substantially continuous morphology, the mechanical properties of the resulting bonded article may be quite poorer than those of the constitutive base metals. Previous work in the field of joining nickel alloys with titanium aluminide has involved changes in the surface of the titanium aluminide by laser-cladding with nickel-containing alloy. However, such cladding has not stopped the formation of continuous layers of potentially unwanted nickel-titanium-aluminum rich layers of the bond line in the joined article.
    In the present invention, a barrier material is used which is interposed between the first and second segments to prevent significant migration of titanium and aluminum by diffusion between segments. An effective barrier material for the purposes of this specification is one which involves the formation of a liquid phase during processing and / or the formation of permanent, deleterious phases and structures such as a substantially continuous layer of a brittle phase or structure or a substantial amount of material prevented with low melting point. As used herein, "permanent" means that the phase or structure is sufficiently robust to adequately survive the processing of the techniques listed herein and thus remain in the linked article. In addition to being an effective barrier to diffusion of these elements, the barrier material can assist bonding by having at least some solubility in titanium aluminide and / or nickel alloys and by having a reaction kinetics with titanium aluminide and nickel alloys such that they themselves are not prone to harmful layers or networks and / or inappropriately high volume fractions of brittle intermetallic phases such as Laves phases, topologically closely packed phases (such as the sigma phase containing iron and chromium) or B2 type body centered cubic phases such as nickel aluminide - (NiAl-) phase to form. According to the invention, the barrier material comprises a primary constituent element present in the barrier material in a concentration of at least about 30% by weight. The primary constituent element is generally a transition metal of Groups 1B, 4B, 5B, 6B, 7B or 8B of the Periodic Table, with the proviso that the following elements of these enumerated groups are excluded from being present as primary constitutive elements due to their propensity to in high concentrations to promote the formation of brittle or low melting point material: titanium, zirconium and nickel. In particular embodiments, the primary constituent element is niobium or tantalum. The niobium or tantalum, in some embodiments, is present in a concentration of at least 50 percent by weight of the barrier material and, in certain other embodiments, is at least 75 percent by weight of the barrier material. Also, other specific embodiments are conceivable in which the barrier material consists essentially of 100% of niobium or tantalum.
    It should be noted that the barrier material is not limited to having only one element present in concentrations greater than about 30 weight percent. Other elements may be present at these concentrations. In addition, the barrier material need not be free of nickel, zirconium and / or titanium, but these elements are generally present, if at all, as minor constituents, meaning that their respective concentrations are not more than about 20% by weight. Further, in some embodiments of the invention, the barrier material may include additional elements such as boron, carbon, zirconium, and other elements that may enhance the ability of the barrier material to diffuse into one or both of the segments, the mechanical properties (such as creep resistance) of the compound improve or otherwise support desirable performance. Finally, in some embodiments of the invention, the barrier material may comprise a plurality of sub-layers, each of which independently comprises one or more of the materials described above. For example, in one embodiment, the barrier material includes a first layer disposed proximate the first segment and a second layer proximate to the second segment. The composition of the material of the first layer is selected to promote advantageous metallurgical bonding to the material of the first segment, and the material of the second layer is selected to promote advantageous metallurgical bonding to the material of the second segment. Factors that lead to advantageous metallurgical bonding include, for example, solubility and / or sufficiently rapid interdiffusion at typical processing temperatures, suppression of deleterious phase formation, and compatibility with other sublayers within the barrier material.
    According to the present invention, the barrier material is interposed between the first and second segments to form a segment assembly comprising the first segment, the second segment, and the inserted barrier material. The insertion of the barrier material can be accomplished using a number of material placement techniques. For example, in one embodiment of the invention, a layer of the barrier material is deposited on one or both of the segments. The settling of the barrier material may be by sputter coating, evaporation or other forms of physical vapor deposition known in the art; by chemical vapor deposition techniques; and / or by other coating techniques, such as thermal spraying or electroplating. Alternatively, a film or other exposed mass of barrier material or powder comprising the barrier material may be introduced between the segments. The thickness of the barrier material selected in any given case depends in part on the time, temperature, and pressure selected to complete the bonding step. If the thickness of the barrier layer is too low given conditions that support relatively fast diffusion (high temperature, long time and / or high pressure), the barrier may not provide sufficient titanium and aluminum diffusion suppression. If the thickness is too strong, again depending on the processing conditions selected, achieving sufficient mass transfer to form a satisfactory metallurgical bond may be difficult. In one embodiment of the invention, the thickness of the barrier material is at least 0.5 micrometers; in some embodiments of the invention, the thickness may be up to about 40 microns. An illustrative embodiment includes the insertion of a barrier layer having a thickness in the range of about 0.5 microns to about 10 microns.
    The segment assembly is then connected. The bonding step is performed using standard diffusion bonding concepts. The assembly is subjected to a pressure, such as greater than about 4 megapascals, which favors close contact between the components of the segment assembly. In some embodiments of the invention, the pressure is in the range of about 4 megapascals to about 7 megapascals. The pressure may be applied by any number of suitable means, including unidirectional pressing or isostatic pressing. While pressurized, the assembly is also heated to a temperature that is sufficiently high to achieve diffusion rates that permit bonding within a practical period of time. The heating is typically conducted in an inert environment such as helium-containing atmosphere, argon-containing atmosphere or under vacuum to avoid excessive oxidation of the materials and / or formation of undesirable levels of deleterious phases such as alpha-2. The actual temperature selected depends in part on the materials used for the various parts of the segment assembly and the time considered practical; in some embodiments of the invention, this temperature is at least about 900 degrees Celsius, and in certain embodiments of the invention, the temperature is in a range of about 900 degrees Celsius to about 1100 degrees Celsius. The time selected depends on the other parameters selected, but in some embodiments of the invention ranges from about 10 minutes to about 4 hours. Upon exposure to the diffusion bonding step, the components of the segment assembly are bonded together to form an intermediate article.
    The intermediate article is then typically heat treated in an inert environment, such as under vacuum or in a noble gas-containing atmosphere, to form a joined article. The heat treatment step can perform various functions. One of the functions of the heat treatment step is to further diffuse the barrier material into the first and second segments, which improves bonding and develops a more homogeneous distribution of the composition across the interfaces between the segments and the barrier material. Another related function is to attenuate harmful phases or structures that may have been formed during the joining step, such as continuous regions of embrittling material or those of low melting point. In general, the heat treatment step involves heating to a temperature sufficiently high, for example, above 900 degrees Celsius, in some embodiments of the invention, to achieve this function within a practical time, but sufficiently low, such as, for example, in some embodiments is about 1300 degrees Celsius and up to about 1200 degrees Celsius in other embodiments to avoid the onset of melting temperature for material in the intermediate article. The intermediate article is held at that temperature for a period of time selected to achieve a desired degree of interdiffusion between the barrier material and the segments; in some embodiments of the invention this time is up to about 50 hours and in specific embodiments is up to about 6 hours.
    Another function of the heat treatment is to develop desired microstructures of the materials in the first and / or second segments. Because desirable microstructures for the alloys involved in the described embodiments often involve the regulated formation and distribution of phases, such as by precipitation enhancement processes, the heat treatment step used may be a multi-stage heat treatment that involves holding the intermediate article at various temperatures during various Stages and, in some cases, cooling steps between stages where the article is cooled at regulated rates to achieve a desired phase size, morphology and / or distribution. The physical metallurgy of titanium aluminide alloys and nickel base superalloys is well developed and the characteristics of desirable microstructures in these alloy systems and various heat treatments used to obtain them will be apparent to those skilled in the art. For example, a desirable titanium aluminide type alloy microstructure in some embodiments may include a gamma phase titanium aluminide matrix and, in some embodiments, one or more other phases such as, but not limited to, alpha phase titanium (hexagonal close packed structured titanium) alpha Double phase (nominal composition Ti3Al) and / or beta phase (body centered cubic titanium) dispersed within the matrix in a morphology and volume fraction effective to control the grain size of the material; in alternative embodiments, a lamellar microstructure comprising, for example, gamma and alpha 2 phases may be desirable. In another example, a desirable microstructure for a nickel-base superalloy, in some embodiments, may be an austenitic-type nickel-containing matrix having a dispersion of gamma prime precipitates of size distribution and volume fraction that are effective to prevent the dislodgement movement and grain size regulate.
    Complex microstructures of the type described above can be achieved by a series of steps performed within the overall heat treatment step and often heating to a first temperature, such as the temperature described above, further into the barrier material and diffusing second segments, then involving changing to a lower second temperature to form, for example, a desired phase in a lamellar structure or as a dispersed precipitate. The heat treatment may involve subsequent stages of heating at progressively lower temperatures to stabilize the microstructure or form other phases. The actual temperatures and times selected depend in part on the type of alloys that are being heat treated, the composition of the phase (s) to be formed, and the desired morphology and size of the phase (s). An illustrative heat treatment regime includes a first heat treatment step at 1050-1080 degrees Celsius for 4-8 hours, followed by oven cooling to a second heat treatment temperature at 850-1000 degrees Celsius for 6-16 hours, followed by oven cooling to ambient temperature.
    In the following, a specific, exemplary embodiment of the inventive method is illustrated. The method comprises inserting a barrier material comprising at least about 30 weight percent niobium, tantalum, or combinations of either or both thereof between a first segment and a second segment to form a segment assembly, the first segment comprising a gamma titanium aluminide material and the second segment comprises a nickel base superalloy; bonding the segment assembly in the solid state at a temperature in the range of about 900 degrees Celsius to about 1300 degrees Celsius, a pressure in the range of about 4 megapascals to about 7 megapascals, and a time effective to establish a metallurgical junction between the first and second produce second segments, wherein an intermediate article is formed; and heat treating the intermediate article by a multi-stage heat treatment to form a joined article.
    The heat treatment step converts the intermediate article into a joined article. Referring to FIG. 1, the article 100 formed by the method described above is characterized by a first part 110 connected to a second part 120 by a transition zone 130. The first part 110 corresponds to the first segment described above and thus comprises the titanium aluminide material, as noted above. The second part 120 corresponds to the second segment described above and thus includes the nickel alloy, as noted above. Transition zone 130 corresponds to the region affected by interdiffusion among the material of the first segment, the material of the second segment, and the barrier material. The actual size and composition of the transition zone will depend on the extent to which the above-noted heat treatment step aids diffusion of the barrier material components to diffuse into the first and second portions 110, 120. With the exception of specific embodiments of the inventive method in which the heat-treating step is carried out to allow the barrier material to completely diffuse away, the transition zone 130 according to the invention is generally characterized by a concentration of a barrier material constituent element which is higher than one Concentration of this element in the first and second portions 110, 120. For example, when niobium is used as the primary constitutive element of the barrier material, the transition zone 130 typically has a higher niobium concentration than either the titanium aluminide alloy of the first portion 110 or the nickel alloy of the second Part 120 can be observed. When the primary constituent element has completely diffused away from the transition zone 130 into the parts 110, 120, the transition zone 130 is characterized by a concentration gradient in the key elements of the alloys forming the respective parts 110, 120. For example, titanium will have a relatively high concentration in the titanium aluminide of the first part 110, a relatively low concentration in the nickel alloy of the second part 120, and a gradient across the transition zone, with the average titanium concentration being between the high concentration and the low concentration.
    The method described above, in some embodiments of the present invention, further provides a transition zone 130 that is substantially free of low melting point material, such as material comprising nickel, titanium, and aluminum. As used herein and throughout the specification, a phase is considered to have a "low melting point" when its melting point is within +/- 100 degrees Celsius of the desired operating temperature of the article 100; In some embodiments, a low melting point phase may have a melting point below 1000 degrees Celsius. Having a low melting point material is undesirable because this material can serve as a starting melting point during processing or operation, and constitutive elements such as titanium and aluminum, which are more advantageously used in the matrix or reinforcing phases, and depending on their concentration or morphology, can serve as nucleation sites and / or as propagation pathways for cracks, can sequester. In particular, the formation of a substantially continuous region of a comparatively brittle phase is not acceptable for high temperature / high stress applications because of its propensity to allow the onset of cracking and its rapid spread through the material. Transition zone 130 is substantially free of such regions in some embodiments of the present invention.
    The article 100 formed by the techniques described above can be used in high temperature components where the parts 110, 120 are located where the characteristics of their respective materials can be most advantageously applied or where their disadvantages are most effectively mitigated can be. Examples of such components include, but are not limited to, components of gas turbine assemblies, such as an aerodynamic turbine profile component (including turbine blades (sometimes referred to as turbine "spoons") and vanes (sometimes referred to as "nozzles") or vane disks (in the English "blisk")). In one example, an aerodynamic turbine profile component used in, for example, an industrial gas turbine is fabricated using the aforementioned techniques to produce a titanium aluminide material in the outer aerodynamic profile sections (ie, those parts of the aerodynamic profile that are in a larger radial distance from the center of the rotor than the inner sections mentioned below), such as the aerodynamic tread peak and tip shroud, with nickel base superalloy being located at, for example, the inner portions of the aerodynamic profile, such as those near lie where the aerodynamic profile is attached to the rotor (gearing, platform, wing root sections, etc.). In this example, in the hybrid configuration of the diffusion bonded component, use is made of the superior high temperature strength and fatigue performance of the superalloy, which is advantageously used in the interior parts of the aerodynamic profile, and the lower density and higher creepage of the titanium aluminide in the outer portions of the aerodynamic profile. According to this illustrative description, the article 100 in FIG. 1 corresponds to the aerodynamic profile, wherein the first portion 110 corresponds to the outer portion (s), such as the tip and / or the tip sheath, comprising the titanium aluminide material while the second portion 120 corresponds to the inner portion (s) comprising the nickel alloy, such as the gearing, platform, and / or wing root portions. One or more transition zones 130 are present in the aerodynamic profile 100 where diffusion bonding occurs to join a titanium aluminide containing section 110 to a nickel alloy containing section 120.
    Examples
    The following examples are presented to further illustrate non-limiting embodiments of the present invention.
    A first cylindrical titanium aluminide alloy segment having a nominal composition of 42.25 weight percent aluminum, 8 weight percent niobium, 1.5 weight percent boron, the remainder being titanium, was cut from ingot and heated at 1340 degrees Celsius for 10 hours. followed by 10 hours at 1000 degrees Celsius to achieve a substantially completely lamellar microstructure. A second cylindrical segment of nickel alloy GTD444 was provided. Both segments were ground to a final finish using 1200 grit sandpaper. A barrier material was provided by depositing 1-8 micrometers of niobium on the GTD-444 segment by magnetron sputtering.
    The segments were brought into contact with each other such that the niobium-coated surface of the GTD444 was an exact surface of the diffusion-bonded junction; that is, the niobium barrier material was interposed between the titanium aluminide alloy of the first segment and the GTD444 material of the second segment. This assembly of segments was then placed in a hot press and bonded under the following conditions: temperature-1020 degrees Celsius; Printing 5 megapascals; Vacuum: 10 <-> <6> to 10 <-> <7> Torr; Time 180 minutes. The bonded assembly was then heat treated at 1080 degrees Celsius for four hours followed by oven cooling to 900 degrees Celsius and then held there for an additional 10 hours, followed by oven cooling to ambient temperature.
    After processing, the final article was cut and the junction was metallographically examined. No voids or cracks were observed at the bond line. No continuous brittle intermetallic phases were observed in the junction and its surrounding regions. Finally, no evidence of eutectic formation such as cracking or initial melting / re-solidification has been observed.
    In contrast, specimens joined in the same manner but without niobium barrier material were observed to have extensive crack formation along the bond line near the nickel alloy segment, and this cracking was associated with the formation of a eutectic phase (the nickel, aluminum Containing titanium and chromium) in a substantially continuous region along the compound.
    While only certain features of the invention have been illustrated and described herein, many modifications and changes will occur to those skilled in the art.
    权利要求:
    Claims (10)
    [1]
    A method for metallurgical solid state bonding of various high temperature materials comprising:inserting a barrier material between a first segment and a second segment to form a segment assembly, wherein the first segment comprises a titanium aluminide material, the second segment comprises a nickel alloy, and the barrier material comprises a primary constitutive element incorporated in the barrier material in one Concentration of at least 30 weight percent of the barrier material is present; wherein the primary constitutive element is a Group 1B, Group 4B (exclusively titanium and zirconium) transition metal element, Group 5B, Group 6B, Group 7B or Group 8B (excluding nickel);bonding the segment assembly in the solid state at a combination of temperature, pressure and time to effect a solid state mass transfer by diffusion between the segments and to produce a metallurgical joint between the first and second segments with the barrier material therebetween, thereby forming an intermediate article is formed; andheat treating the intermediate article to form a linked article.
    [2]
    The method of claim 1, wherein the primary constituent element comprises niobium or tantalum; and orwherein the titanium aluminide material comprises gamma titanium aluminide; and / or wherein the nickel alloy is a nickel base superalloy.
    [3]
    The method of claim 1 or 2, wherein the inserting comprises depositing a layer comprising the barrier material on one or both of the segments.
    [4]
    A method according to any one of the preceding claims, wherein the temperature of the bonding step is in the range of 900 degrees Celsius to 1100 degrees Celsius; and orwherein the pressure of the connecting step is in the range of 4 megapascals to 7 megapascals; and orwherein the joining step is performed in a substantially inert environment.
    [5]
    5. The method of claim 1, wherein heat treating the intermediate article comprises heating the intermediate article to a temperature in a range of from 900 degrees Celsius to 1300 degrees Celsius; and orwherein the heat treatment comprises a multi-stage heat treatment.
    [6]
    6. The method according to any one of the preceding claims comprising:inserting a barrier material comprising at least 30 weight percent niobium, tantalum, or a combination of one or both of these between a first segment and a second segment to form a segment assembly, the first segment comprising a gamma titanium aluminide material; second segment comprises a nickel-base superalloy;bonding the segment assembly in the solid state at a temperature in the range of 900 degrees Celsius to 1300 degrees Celsius, a pressure in the range of 4 megapascals to 7 megapascals, and in a time effective to establish a metallurgical joint between the first and second segments , whereby an intermediate article is formed; andheat treating the intermediate article in a multi-stage heat treatment to form a bonded article.
    [7]
    A joined article (100) obtained by a method according to any one of the preceding claims comprising:a first portion (110) connected to a second portion (120) via a transition zone (130), the first portion (110) comprising a titanium aluminide material, the second portion (120) comprising a nickel alloy, wherein the barrier material a primary constitutive element present in a concentration of at least 30% by weight of the barrier material; wherein the primary constitutive element is a Group 1B, Group 4B (exclusively titanium and zirconium) transition metal element, Group 5B, Group 6B, Group 7B or Group 8B (excluding nickel); and wherein the transition zone (130) comprises a concentration of primary constitutive element that is higher than a concentration of the primary constituent element in the first section (110) and the second section (120).
    [8]
    The article (100) of claim 7, wherein the primary constitutive element comprises niobium, tantalum, or combinations of either or both thereof; and orwherein the transition zone (130) is substantially free of material having a melting point below 1000 degrees Celsius.
    [9]
    The article (100) of claim 7 or 8 wherein the nickel alloy is a nickel base superalloy; and orwherein the titanium aluminide material comprises gamma titanium aluminide.
    [10]
    The article (100) of any one of claims 7 to 9, wherein the article (100) comprises an aerodynamic profile component for a gas turbine assembly.
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    同族专利:
    公开号 | 公开日
    GB2536981A|2016-10-05|
    US20160023439A1|2016-01-28|
    GB2536981B|2017-07-19|
    GB201512408D0|2015-08-19|
    CH709882A2|2016-01-29|
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    法律状态:
    2017-03-15| NV| New agent|Representative=s name: GENERAL ELECTRIC TECHNOLOGY GMBH GLOBAL PATENT, CH |
    2021-02-26| PL| Patent ceased|
    优先权:
    申请号 | 申请日 | 专利标题
    US14/337,850|US20160023439A1|2014-07-22|2014-07-22|Method for joining high temperature materials and articles made therewith|
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